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Different Reactivities of Alkoxy- and Thiocarbene Complexes of Fischer-Type: Formation of (N-Enamino)ethoxycarbene Complexes and Quinolines, Respectively
Karatas, Betuel; Aumann, Rudolf (AMER CHEMICAL SOC, 2010)Alkoxy- and thiocarbene complexes of chromium and tungsten afford different type of products on reaction with (N-aryl)imidoyl chlorides. The (n-butyl)ethoxycarbene complex [(OC)(5)W=C(OEt)n-Bu] and (N-aryl)imidoyl chlorides ...