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Mechanistic investigation of Rh(i)-catalysed asymmetric Suzuki-Miyaura coupling with racemic allyl halides
van Dijk, Lucy; Ardkhean, Ruchuta; Sidera, Mireia; Karabiyikoğlu, Sedef; Sarı, Özlem; Claridge, Timothy DW; Lloyd-Jones, Guy C.; Paton, Robert S.; Fletcher, Stephen P. (Nature Portfolio, 2021)Understanding how catalytic asymmetric reactions with racemic starting materials can operate would enable new enantioselective cross-coupling reactions that give chiral products. Here we propose a catalytic cycle for the ... -
Mechanistic investigation of Rh(i)-catalysed asymmetric Suzuki-Miyaura coupling with racemic allyl halides
Sarı, Özlem; van Dijk, Lucy; Ardkhean, Ruchuta; Sidera, Mireia; Karabıyıkoğlu, Sedef; Claridge, Timothy D. W.; Lloyd-Jones, Guy C.; Paton, Robert S.; Fletcher, Stephen P. (Nature Portfolio, 2021)Understanding how catalytic asymmetric reactions with racemic starting materials can operate would enable new enantioselective cross-coupling reactions that give chiral products. Here we propose a catalytic cycle for the ... -
Synthesis of Benzoxazole-2-carboxylate Derivatives: Electronic- and Position-effect of Functional Groups and Computational Modeling of the Selectivity for Oxazole Ring
Kuzu, Burak; Sarı, Özlem; Erdem, Safiye Sağ; Algül, Öztekin; Mengeş, Nurettin (John Wiley and Sons Inc, 2021)In this study, Mitsunobu reagent, DEAD (diethyl azodicarboxylate) and PPh3, and ethyl-oxalamide derivatives of 2-aminophenol were reacted under mild reaction conditions. As a result of the cyclization reaction, benzoxazole ...
