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Mechanistic investigation of Rh(i)-catalysed asymmetric Suzuki-Miyaura coupling with racemic allyl halides
van Dijk, Lucy; Ardkhean, Ruchuta; Sidera, Mireia; Karabıyıkoğlu, Sedef; Sari, Özlem; Claridge, Timothy D. W.; Lloyd-Jones, Guy C.; Paton, Robert S.; Fletcher, Stephen P. (Nature Portfolıo, 2021)Understanding how catalytic asymmetric reactions with racemic starting materials can operate would enable new enantioselective cross-coupling reactions that give chiral products. Here we propose a catalytic cycle for the ... -
One-pot synthesis of oxazolidinones and five-membered cyclic carbonates from epoxides and chlorosulfonyl isocyanate: theoretical evidence for an asynchronous concerted pathway
Demir, Esra; Sari, Özlem; Çetinkaya, Yasin; Atmaca, Ufuk; Erdem, Safiye Sağ; Çelik, Murat (Beılsteın-Instıtut, 2020)The one-pot reaction of chlorosulfonyl isocyanate (CSI) with epoxides having phenyl, benzyl and fused cyclic alkyl groups in different solvents under mild reaction conditions without additives and catalysts was studied. ...
