| dc.contributor.author | Ozturk, Gulsen | |
| dc.contributor.author | Colak, Mehmet | |
| dc.contributor.author | Demirel, Nadir | |
| dc.date.accessioned | 2019-11-24T20:38:47Z | |
| dc.date.available | 2019-11-24T20:38:47Z | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 0899-0042 | |
| dc.identifier.uri | https://dx.doi.org/10.1002/chir.20934 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12513/2577 | |
| dc.description | WOS: 000289635300002 | en_US |
| dc.description | PubMed ID: 21488104 | en_US |
| dc.description.abstract | Chiral Schiff-bases 3a-f based on ferrocene were designed and synthesized using solvent-free methods by mixing ferrocene carbaldehyde 1 with amino alcohols and amines 2a-f under microwave irradiation and classical method for the enantioselective nitroaldol (Henry) reaction. The Schiff-bases were obtained in shorter reaction times and improved yield under microwave irradiation method over classical method. The highest enantioselectivity was observed in ligand 3e (95% ee) when CH(2)Cl(2) was used as solvent. Chirality 23: 374-378, 2011. (c) 2011 Wiley-Liss, Inc. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | WILEY-BLACKWELL | en_US |
| dc.relation.isversionof | 10.1002/chir.20934 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | ferrocene | en_US |
| dc.subject | microwave irradiation | en_US |
| dc.subject | chiral Schiff-bases | en_US |
| dc.subject | nitro aldol reaction | en_US |
| dc.subject | Henry reaction | en_US |
| dc.title | Solvent-Free Synthesis of Chiral Schiff-Base Ligands Based on Ferrocene under Microwave Irradiation and Application to Enantioselective Nitroaldol (Henry) Reaction | en_US |
| dc.type | article | en_US |
| dc.relation.journal | CHIRALITY | en_US |
| dc.contributor.department | Kırşehir Ahi Evran Üniversitesi, Fen-Edebiyat Fakültesi, Kimya Bölümü | en_US |
| dc.identifier.volume | 23 | en_US |
| dc.identifier.issue | 5 | en_US |
| dc.identifier.startpage | 374 | en_US |
| dc.identifier.endpage | 378 | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
